The coupling between electrons and phonons is one of the fundamental interactions in solids, underpinning a wide range of phenomena, such as resistivity, heat conductivity and superconductivity. However, direct measurements of this coupling for individual phonon modes remain a substantial challenge. In this work, we introduce a new technique for mapping phonon dispersions and electron–phonon coupling (EPC) in van der Waals (vdW) materials. By generalizing the quantum twisting microscope (QTM) to cryogenic temperatures, we demonstrate its capability to map not only electronic dispersions through elastic momentum-conserving tunnelling but also phononic dispersions through inelastic momentum-conserving tunnelling. Crucially, the inelastic tunnelling strength provides a direct and quantitative measure of the momentum and mode-resolved EPC. We use this technique to measure the phonon spectrum and EPC of twisted bilayer graphene (TBG) with twist angles larger than 6°. Notably, we find that, unlike standard acoustic phonons, whose coupling to electrons diminishes as their momentum tends to zero, TBG exhibits a low-energy mode whose coupling increases with decreasing twist angle. We show that this unusual coupling arises from the modulation of the interlayer tunnelling by a layer-antisymmetric ‘phason’ mode of the moiré system. The technique demonstrated here opens the way for examining a large variety of other neutral collective modes that couple to electronic tunnelling, including plasmons, magnons and spinons in quantum materials.
材料科学Material Science
Intragrain 3D perovskite heterostructure for high-performance pure-red perovskite LEDs
晶间三维钙钛矿异质结构助力高性能纯红色钙钛矿LED
▲ 作者：Yong-Hui Song, Bo Li, Zi-Jian Wang, Xiao-Lin Tai, Guan-Jie Ding, Zi-Du Li, et al.
该策略产生了明亮高效的纯红色PeLED，具有24600 cd m-2的高亮度，24.2%的峰值外量子效率，以及极低的效率骤降，在22670 cd m-2的高亮度下仍保持10.5%的外量子效率。
▲ Abstract：
Metal-halide perovskites are promising light-emitter candidates for next-generation light-emitting diodes (LEDs). Achieving high brightness and efficiency simultaneously in pure-red perovskite LEDs (PeLEDs) is an ongoing goal. Three-dimensional (3D) CsPbI3-xBrx?emitters have excellent carrier transport capability and high colour purity, which could allow efficient and ultrabright pure-red PeLEDs. However, such devices are prone to efficiency roll-off, resulting in low efficiency and low brightness under high current density. Here, by using electrically excited transient absorption spectroscopy, we discovered the efficiency roll-off was induced by hole leakage. Therefore, we developed a CsPbI3-xBrx?intragrain heterostructure containing narrow bandgap emitters and wide bandgap barriers to confine the injected carriers. The wide bandgap barrier was incorporated by introducing strongly bonding molecules into the [PbX6]4-?framework to expand the 3D CsPbI3-xBrx?lattice. This strategy resulted in bright and efficient pure-red PeLEDs, with a high brightness of 24,600 cd m-2, maximum external quantum efficiency of 24.2% and low efficiency roll-off, maintaining a 10.5% external quantum efficiency at a high luminance of 22,670 cd m-2.
Structurally complex phase engineering enables hydrogen-tolerant Al alloys
Hydrogen embrittlement (HE) impairs the durability of aluminium (Al) alloys and hinders their use in a hydrogen economy. Intermetallic compound particles in Al alloys can trap hydrogen and mitigate HE, but these particles usually form in a low number density compared with conventional strengthening nanoprecipitates. Here we report a size-sieved complex precipitation in Sc-added Al–Mg alloys to achieve a high-density dispersion of both fine Al3Sc nanoprecipitates and in situ formed core-shell Al3(Mg,Sc)2/Al3Sc nanophases with high hydrogen-trapping ability. The two-step heat treatment induces heterogeneous nucleation of the Samson-phase Al3(Mg,Sc)2?on the surface of Al3Sc nanoprecipitates that are only above 10nm in size. The size dependence is associated with Al3Sc nanoprecipitate incoherency, which leads to local segregation of magnesium and triggers the formation of Al3(Mg,Sc)2. The tailored distribution of dual nanoprecipitates in our Al–Mg–Sc alloy provides about a 40% increase in strength and nearly five times improved HE resistance compared with the Sc-free alloy, reaching a record tensile uniform elongation in Al alloys charged with H up to 7ppmw. We apply this strategy to other Al–Mg-based alloys, such as Al–Mg–Ti–Zr, Al–Mg–Cu–Sc and Al–Mg–Zn–Sc alloys. Our work showcases a possible route to increase hydrogen resistance in high-strength Al alloys and could be readily adapted to large-scale industrial production.
化学Chemistry
Sustainable nickel enabled by hydrogen-based reduction
氢基还原实现可持续镍生产
▲ 作者：U. Manzoor, L. Mujica Roncery, D. Raabe & I. R. Souza Filho
Nickel is a critical element in the shift to sustainable energy systems, with the demand for nickel projected to exceed 6 million tons annually by 2040, largely driven by the electrification of the transport sector. Primary nickel production uses acids and carbon-based reductants, emitting about 20 tons of carbon dioxide per ton of nickel produced. Here we present a method using fossil-free hydrogen-plasma-based reduction to extract nickel from low-grade ore variants known as laterites. We bypass the traditional multistep process and combine calcination, smelting, reduction and refining into a single metallurgical step conducted in one furnace. This approach produces high-grade ferronickel alloys at fast reduction kinetics. Thermodynamic control of the atmosphere of the furnace enables selective nickel reduction, yielding an alloy with minimal impurities (<0.04 wt% silicon, approximately 0.01 wt% phosphorus and <0.09 wt% calcium), eliminating the need for further refining. The proposed method has the potential to be up to about 18% more energy efficient while cutting direct carbon dioxide emissions by up to 84% compared with current practice. Our work thus shows a sustainable approach to help resolve the contradiction between the beneficial use of nickel in sustainable energy technologies and the environmental harm caused by its production.
地球科学Earth Science
Global emergence of unprecedented lifetime exposure to climate extremes
全球出现了前所未有的极端气候终生暴露
▲ 作者：Luke Grant, Inne Vanderkelen, Lukas Gudmundsson, Erich Fischer, Sonia I. Seneviratne & Wim Thiery
Climate extremes are escalating under anthropogenic climate change. Yet, how this translates into unprecedented cumulative extreme event exposure in a person’s lifetime remains unclear. Here we use climate models, impact models and demographic data to project the number of people experiencing cumulative lifetime exposure to climate extremes above the 99.99th percentile of exposure expected in a pre-industrial climate. We project that the birth cohort fraction facing this unprecedented lifetime exposure to heatwaves, crop failures, river floods, droughts, wildfires and tropical cyclones will at least double from 1960 to 2020 under current mitigation policies aligned with a global warming pathway reaching 2.7 °C above pre-industrial temperatures by 2100. Under a 1.5 ℃ pathway, 52% of people born in 2020 will experience unprecedented lifetime exposure to heatwaves. If global warming reaches 3.5 °C by 2100, this fraction rises to 92% for heatwaves, 29% for crop failures and 14% for river floods. The chance of facing unprecedented lifetime exposure to heatwaves is substantially larger among population groups characterized by high socioeconomic vulnerabilities. Our results call for deep and sustained greenhouse gas emissions reductions to lower the burden of climate change on current young generations.
Melt focusing along lithosphere–asthenosphere boundary below Axial volcano
沿轴向火山下方岩石圈-软流圈边界的熔体聚集
▲ 作者：G. M. Kent, A. F. Arnulf, S. C. Singh, H. Carton, A. J. Harding & S. Saustrup
Beneath oceanic spreading centres, the lithosphere–asthenosphere boundary (LAB) acts as a permeability barrier that focuses the delivery of melt from deep within the mantle towards the spreading axis. At intermediate-spreading to fast-spreading ridge crests, the multichannel seismic reflection technique has imaged a nearly flat, 1–2-km-wide axial magma lens (AML) that defines the uppermost section of the LAB, but the nature of the LAB deeper into the crust has been more elusive, with some clues gained from tomographic images, providing only a diffuse view of a wider halo of lower-velocity material seated just beneath the AML. Here we present 3D seismic reflection images of the LAB extending deep (5–6 km) into the crust beneath Axial volcano, located at the intersection of the Juan de Fuca Ridge and the Cobb–Eickelberg hotspot. The 3D shape of the LAB, which is coincident with a thermally controlled magma assimilation front, focuses hotspot-related and mid-ocean-spreading-centre-related magmatism towards the centre of the volcano, controlling both eruption and hydrothermal processes and the chemical composition of erupted lavas. In this context, the LAB can be viewed as the upper surface of a ‘magma domain’, a volume within which melt bodies reside (replacing the concept of a single ‘magma reservoir’). Our discovery of a funnel-shaped, crustal LAB suggests that thermally controlled magma assimilation could be occurring along this surface at other volcanic systems, such as Iceland.
